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536 lines (496 loc) · 33.5 KB
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// This compiler flag causes input/output units on the Thermodynamic Properties in IF97.h
// to take pressure units of [MPa] and Energy units of [kJ] for comparison with IAPWS
// table values. If not set, the default behavior of IF97.h is to use straight SI units
// with pressure in [Pa] and enthalpy in [J].
#define IAPWS_UNITS
// This compiler flag causes the Region 3 v(p,T) function to be iterated to improve
// accuracy. If not defined, the Region 3 v(p,T) function will return the direct
// value from the supplementary release IAPWS SR5-05(2016), which may be in error
// by up to 1E-6 of the iterative solution in Region 3.
#define REGION3_ITERATE
#include "IF97.h"
#include <iostream>
#include <stdio.h>
#include <iomanip>
#include <chrono>
int main() {
using namespace IF97;
using namespace std;
using namespace chrono;
cout << " Verification Tables" << std::endl << std::endl;
std::cout << "The tables below are printed for verification purposes. Developers should check the error levels below\n";
std::cout << "to verify that there are no code regressions in new code updates. Unless otherwise noted, tables are\n";
std::cout << "reproduced from the \"Revised Release on the IAPWS Industrial Formulation 1997\" IAPWS R7-97(2012).\n\n\n";
//
// IAPWS-IF97 Verification Tables 5, 15, 33 from IAPWS R7-97(2012)
//
// Print all three tables together since they are all T,p tables and follow with a table of relative error.
//
double T[12] = {300, 300, 500, 300, 700, 700, 650, 650, 750, 1500, 1500, 2000};
double p[12] = {3, 80, 3, 0.0035, 0.0035, 30, 25.5837018, 22.2930643, 78.3095639, 0.5, 30, 30};
double v[12] = {0.00100215168, 0.000971180894, 0.001202418, 39.4913866, 92.3015898, 0.00542946619,
0.002, 0.005, 0.002, 1.3845509, 0.0230761299, 0.0311385219};
double h[12] = { 115.331273, 184.142828, 975.542239, 2549.91145, 3335.68375, 2631.49474, 1863.43019,
2375.12401, 2258.68845, 5219.76855, 5167.23514, 6571.22604};
double u[12] = {112.324818, 106.448356, 971.934985, 2411.6916, 3012.62819, 2468.61076, 1812.26279,
2263.65868, 2102.06932, 4527.4931, 4474.95124, 5637.07038};
double s[12] = {0.392294792, 0.368563852, 2.58041912, 8.52238967, 10.1749996, 5.17540298,
4.05427273, 4.85438792, 4.46971906, 9.65408875, 7.72970133, 8.53640523};
double cp[12] = { 4.17301218, 4.01008987, 4.65580682, 1.91300162, 2.08141274, 10.3505092,
13.8935717, 44.6579342, 6.34165359, 2.61609445, 2.72724317, 2.88569882};
double w[12] = { 1507.73921, 1634.69054, 1240.71337, 427.920172, 644.289068, 480.386523,
502.005554, 383.444594, 760.696041, 917.06869, 928.548002, 1067.36948};
double sum2 = 0, RMS1 = 0, RMS2 = 0;
int ecount = 0;
const char* div1 = "__________________________________________________________________________________________________________________\n";
const char* div2 = "_______________________________________________________\n";
cout << div1;
cout << " Verification Tables 5, 15, 33, and 42" << endl;
cout << " (Regions 1, 2, 3, 5 - 3 pts. each)" << endl;
cout << div1;
cout << div1;
cout << " T p v h u s cp w" << endl;
cout << " [K] [MPa] [m^3/kg] [kJ/kg] [kJ/kg] [kJ/kg-K] [kJ/kg-K] [m/s]" << endl;
cout << div1;
for (int i = 0; i < 12; i++) {
cout << " " << right << fixed << setprecision(0) << setw(4) << T[i];
cout << resetiosflags(ios_base::fixed);
cout << setprecision(7) << setw(10) << p[i];
if (i >= 6 && i <= 8) {
cout << fixed << setprecision(3) << setw(16) << 1.0 / rhomass_Tp(T[i], p[i]);
cout << resetiosflags(ios_base::fixed);
cout << scientific << setprecision(8) << setw(16);
} else {
cout << scientific << setprecision(8) << setw(16) << 1.0 / rhomass_Tp(T[i], p[i]);
};
cout << setw(16) << hmass_Tp(T[i], p[i]);
cout << setw(16) << umass_Tp(T[i], p[i]);
cout << setw(16) << smass_Tp(T[i], p[i]);
cout << setw(16) << cpmass_Tp(T[i], p[i]);
cout << setw(16) << speed_sound_Tp(T[i], p[i]);
cout << " " << endl;
};
cout << div1;
cout << " RELATIVE ERROR" << endl;
cout << div1;
cout << " T p v h u s cp w" << endl;
cout << " [K] [MPa] [error] [error] [error] [error] [error] [error]" << endl;
cout << div1;
for (int i = 0; i < 12; i++) {
cout << " " << right << fixed << setprecision(0) << setw(4) << T[i];
cout << resetiosflags(ios_base::fixed);
cout << setprecision(7) << setw(10) << p[i];
cout << " " << scientific << setprecision(4) << setw(10) << abs(1.0 / rhomass_Tp(T[i], p[i]) - v[i]) / v[i];
sum2 += powi((1.0 / rhomass_Tp(T[i], p[i]) - v[i]) / v[i], 2); ecount++;
cout << " " << setw(10) << abs(hmass_Tp(T[i], p[i]) - h[i]) / h[i];
sum2 += powi((hmass_Tp(T[i], p[i]) - h[i]) / h[i], 2); ecount++;
cout << " " << setw(10) << abs(umass_Tp(T[i], p[i]) - u[i]) / u[i];
sum2 += powi((umass_Tp(T[i], p[i]) - u[i]) / u[i], 2); ecount++;
cout << " " << setw(10) << abs(smass_Tp(T[i], p[i]) - s[i]) / s[i];
sum2 += powi((smass_Tp(T[i], p[i]) - s[i]) / s[i], 2); ecount++;
cout << " " << setw(10) << abs(cpmass_Tp(T[i], p[i]) - cp[i]) / cp[i];
sum2 += powi((cpmass_Tp(T[i], p[i]) - cp[i]) / cp[i], 2); ecount++;
cout << " " << setw(10) << abs(speed_sound_Tp(T[i], p[i]) - w[i]) / w[i];
sum2 += powi((speed_sound_Tp(T[i], p[i]) - w[i]) / w[i], 2); ecount++;
cout << " " << endl;
};
RMS1 = sqrt(sum2 / ecount);
cout << div1;
cout << "NOTE 1: Relative errors above should be on the order of 1E-8 or lower." << endl;
cout << " The RMS all relative errors (" << ecount << ") is " << scientific << setprecision(3) << RMS1 << endl << endl;
cout << "NOTE 2: The values of v in region 3 in the above table (rows 6-8) are evaluated first using the supplemental\n"
<< " backward equations for v(T,p) from IAPWS SR5-05(2016). These values are then used as the initial\n"
<< " values to iterate on the p(T,v) equation from IAPWS R7-97(2012). IAPWS explains that the values\n"
<< " from v(T,p) could be used directly, but that they may be up to 1E-6 in error. By iterating on\n"
<< " p(T,v) using the v(T,p) values as initial estimates, the relative error is reduced to the order\n"
<< " of 1E-8 and computation time is greatly reduced." << endl << endl << endl;
//**************************************************************************************************************
//
// IAPWS-IF97 Verification Tables 5, 13 from IAPWS SR5-05(2016)
//
// This section provides verification of the Region 3, algebraic
//
//**************************************************************************************************************
double pv3[51] = {80, 50, 80, 20, 30, 26, 30, 26, 30, 26, 30, 23.6, 24, 23.6, 24, 23.6, 24,
23.5, 24, 23, 24, 22.6, 23, 22.6, 22.8, 22.6, 22.8, 22.6, 22.8, 22.6, 22.8, 21.1, 21.8, 21.1,
21.8, 19.1, 20, 17, 20, 21.5, 22, 22.5, 22.3, 22.15, 22.3, 22.11, 22.3, 22, 22.064, 22, 22.064};
double Tv3[51] = {670, 710, 750, 630, 650, 656, 670, 661, 675, 671, 690, 649, 650, 652, 654, 653, 655,
655, 660, 660, 670, 646, 646, 648.6, 649.3, 649, 649.7, 649.1, 649.9, 649.4, 650.2, 640, 643, 644,
648, 635, 638, 626, 640, 644.6, 646.1, 648.6, 647.9, 647.5, 648.1, 648, 649, 646.84, 647.05, 646.89, 647.15};
double vv3[51] = {1.503831359E-3, 2.204728587E-3, 1.97369294E-3, 1.761696406E-3, 1.819560617E-3, 2.24558772E-3, 2.506897702E-3, 2.970225962E-3,
3.004627086E-3, 5.019029401E-3, 4.656470142E-3, 2.163198378E-3, 2.166044161E-3, 2.651081407E-3, 2.967802335E-3, 3.273916816E-3,
3.550329864E-3, 4.545001142E-3, 5.100267704E-3, 6.109525997E-3, 6.427325645E-3, 2.117860851E-3, 2.062374674E-3, 2.53306378E-3,
2.572971781E-3, 2.923432711E-3, 2.913311494E-3, 3.131208996E-3, 3.221160278E-3, 3.715596186E-3, 3.66475479E-3, 1.970999272E-3,
2.043919161E-3, 5.251009921E-3, 5.256844741E-3, 1.932829079E-3, 1.985387227E-3, 8.483262001E-3, 6.227528101E-3, 2.268366647E-3,
2.296350553E-3, 2.83237326E-3, 2.811424405E-3, 3.694032281E-3, 3.622226305E-3, 4.528072649E-3, 4.556905799E-3, 2.698354719E-3,
2.717655648E-3, 3.798732962E-3, 3.70194001E-3};
cout << div2;
cout << " Verification Tables 5, 13 - IAPWS SR5-05(2016)" << endl;
cout << " (Region 3 direct formulation for v(T,p))" << endl;
cout << div2;
cout << div2;
cout << " T p v Error" << endl;
cout << " [K] [MPa] [m^3/kg] [rel]" << endl;
cout << div2;
sum2 = 0; ecount = 0;
cout << resetiosflags(ios_base::fixed);
for (int i = 0; i < 51; i++) {
cout << defaultfloat << setprecision(5) << setw(10) << Tv3[i];
cout << setw(10) << pv3[i];
cout << scientific << setprecision(8) << setw(16) << 1.0 / rhomass_Tp(Tv3[i], pv3[i]) << " ";
cout << scientific << setprecision(4) << setw(10) << abs(1.0 / rhomass_Tp(Tv3[i], pv3[i]) - vv3[i]) / vv3[i] << " ";
sum2 += powi((1.0 / rhomass_Tp(Tv3[i], pv3[i]) - vv3[i]) / vv3[i], 2); ecount++;
cout << endl;
};
cout << div1;
// RMS2 = sqrt(sum2 / ecount); // Don't print RMS here since it will be high (see Note 3)
// cout << "RMS Error = " << scientific << setprecision(3) << RMS2 << endl << endl;
cout << "NOTE 3: Error values above should be on the order of 1E-6 or lower, except the last dozen, which are very near\n";
cout << " the critical point and can be as high as 1.5E-2. However, since the calculated values are actually\n";
cout << " using the IF97 iterative solution in region 3, the error is actually the distance from these initial guess\n";
cout << " values to the more accurate iterative solution, not the actual error in the formulation. See NOTE 3 below.\n";
cout << " To see the actual error in this explicit equation, undefine the REGION3_ITERATE flag at the top of this \n";
cout << " file to turn off the iterative solution and provide just the explicit results from v(p,T). Doing so will\n";
cout << " increase the error in the previous verification table to the order of 1E-6 for points in region 3, but\n";
cout << " drop the relative error in this table to on the order of 1E-10.\n\n";
cout << "NOTE 4: IAPWS-IF97 is covered by a basic equation for the Helmholtz free energy, f(v,T). In some steam\n";
cout << " power cycles, thermodynamic properties as a function of (p,T) are required in region 3. This\n";
cout << " requires iteration of the Helmhotz equation to find v from p and T. To avoid this iterative\n";
cout << " solution, IAPWS has provided a supplementary release with explicit equations for v as a function\n";
cout << " of T and P in region 3, dramatically speeding up these calculations.\n\n\n\n";
//**************************************************************************************************************
//
// IAPWS-IF97 Verification Tables 35 & 36 from IAPWS R7-97(2012)
//
// This section provides verification of the Region 3, algebraic
//
//**************************************************************************************************************
double Ts[3] = {300.0, 500.0, 600.0};
double ps[3] = {0.1, 1.0, 10.0};
double pact[3] = {0.353658941E-2, 0.263889776E+1, 0.123443146E+2};
double Tact[3] = {0.372755919E+3, 0.453035632E+3, 0.584149488E+3};
double Tout = 0, pout = 0, Terr = 0, perr = 0;
sum2 = 0; ecount = 0;
printf("_______________________________________________________________________\n");
printf(" Region 4: Saturation Temperature/Pressure Equations \n");
printf("_______________________________________________________________________\n");
printf("_______________________________________________________________________\n");
printf(" Table 35 | Table 36 \n");
printf(" Saturation Pressures | Saturation Temperatures \n");
printf("__________________________________|____________________________________\n");
printf(" T/K p/MPa rel err | p/MPa T/K rel err \n");
printf("__________________________________|____________________________________\n");
for (int i = 0; i < 3; i++) {
pout = psat97(Ts[i]);
perr = abs(pout - pact[i]) / pact[i];
sum2 += powi((pout - pact[i]) / pact[i], 2); ecount++;
Tout = Tsat97(ps[i]);
Terr = abs(Tout - Tact[i]) / Tact[i];
sum2 += powi((Tout - Tact[i]) / Tact[i], 2); ecount++;
printf(" %3.0f %11.9e %8.1e | %4.1f %11.8e %8.1e\n", Ts[i], pout, perr, ps[i], Tout, Terr);
};
printf("_______________________________________________________________________\n");
printf(" Relative errors above should be on the order of 1E-9 or lower.\n");
RMS1 = sqrt(sum2 / ecount);
printf(" The RMS of all relative errors (%d) is %5.3e\n\n", ecount, RMS1);
//
// Timing test for Tsat97 and psat97 vectorization
//
printf("_______________________________________________________________________\n");
printf(" Timing Test for Tsat97 and psat97 optimization \n");
printf("_______________________________________________________________________\n");
double tsat, psat;
double pt = get_ptrip(); // triple point pressure
double pc = get_pcrit(); // critical point pressure
double n = 100000; // number of calls to Tsat97 for timing test
double dp = (pc - pt) / n; // step size
high_resolution_clock::time_point start, end;
start = high_resolution_clock::now(); // start time
for (double p = pt; p <= pc; p += dp) { // loop over n calls to Tsat97
tsat = Tsat97(p);
}
end = high_resolution_clock::now(); // end time
duration<double> dif = duration_cast<duration<double>>(end - start) * 1000.0; // time in ms
printf(" Timing (100k Tsat calls): %5g ms\n",dif.count());
double Tt = get_Ttrip(); // triple point temperature
double Tc = get_Tcrit(); // critical point temperature
double dt = (Tc - Tt) / n; // step size
start = high_resolution_clock::now(); // start time
for (double T = Tt; T <= Tc; T += dt) { // loop over n calls to psat97
psat = psat97(T);
}
end = high_resolution_clock::now(); // end time
dif = duration_cast<duration<double>>(end - start) * 1000.0; // time in ms
printf(" Timing (100k psat calls): %5g ms\n",dif.count());
printf("_______________________________________________________________________\n\n\n\n");
cout << div1;
cout << " REVERSE FUNCTIONS\n";
cout << div1 << endl << endl;
// ******************************************************************************
// Reverse Functions T(p,h) & T(p,s) from IAPWS R7-97(2012) & *IAPWS SR3-03(2014)
// ******************************************************************************
cout << div1;
cout << " Reverse Functions T(p,h) and T(p,s)\n\n";
cout << "The verification table below contains contain the published T(p,h) and T(p,s) values for verification of computer\n";
cout << "programs from Table 7 (p. 11) and Table 24 (p. 25) of [IAPWS R7-97(2012)], as well as Table 5 (p. 8) of Reference\n";
cout << "[IAPWS SR3-03(2014)].\n";
cout << div1;
// Verification Points for Reverse Functions T(p,h) & T(p,s)
char* region[18] = {"1", "1", "1", "2a", "2a", "2a", "2b", "2b", "2b", "2c", "2c", "2c", "3a", "3a", "3a", "3b", "3b", "3b"};
double pR[18] = {3.0, 80.0, 80.0, // Region 1, Table 7
0.001, 3.0, 3.0, // Region 2a, Table 24
5.0, 5.0, 25.0, // Region 2b, Table 24
40.0, 60.0, 60.0, // Region 2c, Table 24
20.0, 50.0, 100.0, // Region 3a, Table 5*
20.0, 50.0, 100.0}; // Region 3b, Table 5*
double hR[18] = {500, 500, 1500, // Region 1, Table 7
3000, 3000, 4000, // Region 2a, Table 24
3500, 4000, 3500, // Region 2b, Table 24
2700, 2700, 3200, // Region 2c, Table 24
1700, 2000, 2100, // Region 3a, Table 5*
2500, 2400, 2700}; // Region 3b, Table 5*
double TR[18] = { 391.798509, 378.108626, 611.041229, // Region 1, Table 7
534.433241, 575.373370, 1010.77577, // Region 2a, Table 24
801.299102, 1015.31583, 875.279054, // Region 2b, Table 24
743.056411, 791.137067, 882.756860, // Region 2c, Table 24
629.3083892,690.5718338,733.6163014, // Region 3a, Table 5*
641.8418053,735.1848618,842.0460876 }; // Region 3b, Table 5*
//
double pRs[18] = {3.0, 80.0, 80.0, // Region 1, Table 7
0.1, 0.1, 2.5, // Region 2a, Table 24
8.0, 8.0, 90.0, // Region 2b, Table 24
20.0, 80.0, 80.0, // Region 2c, Table 24
20.0, 50.0, 100.0, // Region 3a, Table 5*
20.0, 50.0, 100.0}; // Region 3b, Table 5*
double sR[18] = { 0.5, 0.5, 3.0, // Region 1, Table 7
7.5, 8.0, 8.0, // Region 2a, Table 24
6.0, 7.5, 6.0, // Region 2b, Table 24
5.75,5.25,5.75, // Region 2c, Table 24
3.8, 3.6, 4.0, // Region 3a, Table 5*
5.0, 4.5, 5.0}; // Region 3b, Table 5*
double TRs[18] = {307.842258, 309.979785, 565.899909, // Region 1, Table 7
399.517097, 514.127081, 1039.84917, // Region 2a, Table 24
600.48404, 1064.95556, 1038.01126, // Region 2b, Table 24
697.992849, 854.011484, 949.017998, // Region 2c, Table 24
628.2959869, 629.7158726, 705.6880237, // Region 3a, Table 5*
640.1176443, 716.3687517, 847.4332825}; // Region 3b, Table 5*
sum2 = 0; ecount = 0;
cout << div1;
printf("Region| p/MPa h/(kJ/kg) T/K rel. err. | p/MPa s/(kJ/kg/K) T/K rel. err.\n");
cout << div1;
for (int i = 0; i < 18; i++) {
Tout = T_phmass(pR[i], hR[i]);
Terr = abs(Tout - TR[i]) / TR[i];
sum2 += powi((Tout - TR[i]) / TR[i], 2); ecount++;
printf(" %2s | %5g %4.0f %15.8e %10.3e ",region[i],pR[i],hR[i],Tout,Terr);
Tout = T_psmass(pRs[i], sR[i]);
Terr = abs(Tout - TRs[i]) / TRs[i];
sum2 += powi((Tout - TRs[i]) / TRs[i], 2); ecount++;
printf("| %5g %4.2g %15.8e %10.3e\n", pRs[i], sR[i], Tout, Terr);
}
cout << div1;
RMS1 = sqrt(sum2 / ecount);
cout << "Relative errors above should be on the order of 1E-9 or lower.\n";
cout << "The RMS of all relative errors (" << ecount << ") is " << scientific << setprecision(3) << RMS1 << endl << endl;
cout << "* NOTE 5: The Region 3a, 3b validation comes from Table 5 & 12 of the 2014\n";
cout << " \"Revised Supplementary Release on Backward Equations for the \n";
cout << " functions T(p,h), v(p,h) and T(p,s), v(p,s) for Region 3\"\n";
cout << " [IAPWS SR3-03(2014)]\" \n\n";
cout << " NOTE 6: While [IAPWS SR3-03(2014)] provides direct reverse functions for v(p,h) and v(p,s)\n";
cout << " in region 3, these are not used in this implementation because [IAPWS R7-97(2012)]\n";
cout << " does not provide them for regions 1, 2, and 5. Instead, the reverse functions T(p,h)\n";
cout << " and T(p,s) are used to determine T, which is then used to determine v from v(p,T) in\n ";
cout << " all regions. This provides a consistent approach for all regions.\n\n\n\n";
// ******************************************************************************
// Reverse Functions P(h,s) from IAPWS SR2-01(2014) & IAPWS SR4-04(2014)
// ******************************************************************************
cout << div2;
cout << " Reverse Function p(h,s)\n\n";
cout << "The Enthalpy-Entropy table below contains the published p(h,s) values for \n";
cout << "verification of computer programs from Table 3 (p.6) and Table 9 (p.10) of \n";
cout << "[IAPWS SR2-01(2014)], as well as Table 5 (p.10) of [IAPWS SR4-04(2014)].\n";
cout << "The last three values are Tsat points from Table 29 of [IAPWS SR4-04(2014)].\n";
cout << div2;
// Verification Points for Reverse Functions p(h,s)
double hv[21] = {0.001, 90, 1500, // Region 1, Table 3
2800, 2800, 4100, // Region 2a, Table 9
2800, 3600, 3600, // Region 2b, Table 9
2800, 2800, 3400, // Region 2c, Table 9
1700, 2000, 2100, // Region 3a, Table 5
2600, 2400, 2700, // Region 3b, Table 5
1800, 2400, 2500}; // Region 4, Table 29
double sv[21] = {0.0, 0.0, 3.4, // Region 1, Table 3
6.5, 9.5, 9.5, // Region 2a, Table 9
6.0, 6.0, 7.0, // Region 2b, Table 9
5.1, 5.8, 5.8, // Region 2c, Table 9
3.8, 4.2, 4.3, // Region 3a, Table 5
5.1, 4.7, 5.0, // Region 3b, Table 5
5.3, 6.0, 5.5}; // Region 4, Table 29
double ptv[21] = {9.800980614e-4, 91.92954727, 58.68294423, // Region 1, Table 3
1.371012767, 1.879743844e-3, 0.1024788997, // Region 2a, Table 9
4.793911442, 83.95519209, 7.527161441, // Region 2b, Table 9
94.3920206, 8.414574124, 83.76903879, // Region 2c, Table 9
25.55703246, 45.40873468, 60.7812334, // Region 3a, Table 5
34.34999263, 63.63924887, 88.39043281, // Region 3b, Table 5
346.8475498, 425.1373305, 522.5579013}; // Region 4, Table 29
sum2 = 0; ecount = 0;
cout << div2;
printf(" | h s P error\n");
printf("Region| [kJ/kg] [kJ/kg/K] [MPa] [rel]\n");
cout << div2;
for (int i = 0; i < 18; i++) {
pout = p_hsmass(hv[i], sv[i]);
perr = abs(pout - ptv[i]) / ptv[i];
sum2 += powi((pout - ptv[i]) / ptv[i], 2); ecount++;
printf(" %2s | %5g %5g %15.8e %10.3e \n", region[i], hv[i], sv[i], pout, perr);
}
cout << div2;
printf(" | Tsat/[K]\n");
cout << div2;
for (int i = 18; i < 21; i++) {
Tout = T_hsmass(hv[i], sv[i]);
Terr = abs(Tout - ptv[i]) / ptv[i];
sum2 += powi((Tout - ptv[i]) / ptv[i], 2); ecount++;
printf(" %2s | %5g %5g %15.8e %10.3e \n", "4", hv[i], sv[i], Tout, Terr);
}
cout << div2;
RMS1 = sqrt(sum2 / ecount);
cout << "Relative errors above should be on the order of 1E-10 or lower.\n";
cout << "The RMS of all relative errors (" << ecount << ") is " << scientific << setprecision(3) << RMS1 << endl << endl << endl;
cout << div1;
cout << " TRANSPORT PROPERTIES\n";
cout << div1 << endl << endl;
// ******************************************************************************
// VISCOSITY Verification Values from IAPWS R12-08
// ******************************************************************************
cout << div2;
cout << " Water Viscosity Verification\n\n";
cout << "Pressure and Temperature points based on the tabulated computer program\n";
cout << "verification values from [IAPWS R12-08], page 8, Table 4. Per guidance\n";
cout << "from IAPWS, the critical enhancement, mu2, is set to 1, resulting in\n";
cout << "slightly greater error in the lower portion of this table, very near\n";
cout << "the critical point. This function is temperature and density based.\n ";
cout << "The density is determined from the IF97 formulation for the function\n";
cout << "visc_Tp(T,p). However, the direct density function, visc_TRho(T,rho)\n";
cout << "is used for the verificsation table below.\n";
cout << div2;
double Tmu[17] = {298.15, 298.15, 373.15, 433.15, 433.15, 873.15, 873.15, 873.15, 1173.15,
1173.15, 1173.15, 647.35, 647.35, 647.35, 647.35, 647.35, 647.35};
double rhomu[17] = {998, 1200, 1000, 1, 1000, 1, 100, 600, 1, 100, 400, 122, 222, 272, 322, 372, 422};
double mu[17] = {889.7351, 1437.649467, 307.883622, 14.538324, 217.685358, 32.619287, 35.802262, 77.430195, 44.217245,
47.640433, 64.154608, 25.520677, 31.337589, 36.228143, 42.961579, 45.688204, 49.436256};
double mout = 0, merr = 0;
sum2 = 0; ecount = 0;
cout << " T rho visc error\n";
cout << " [K] [kg/m^3] [uPa*s] [rel]\n";
cout << div2;
for (int i = 0; i < 11; i++) {
mout = visc_TRho(Tmu[i], rhomu[i]) * 1.0e6; // convert from Pa-s to uPa-s
merr = abs(mout - mu[i]) / mu[i];
sum2 += merr * merr; ecount++;
printf(" %7.2f %5g %14.6f %10.3e \n", Tmu[i], rhomu[i], mout, merr);
}
cout << div2;
RMS1 = sqrt(sum2 / ecount); // RMS1 includes first eleven points away from critical point
sum2 = 0; ecount = 0;
for (int i = 11; i < 17; i++) {
mout = visc_TRho(Tmu[i], rhomu[i]) * 1.0e6; // convert from Pa-s to uPa-s
merr = abs(mout - mu[i]) / mu[i];
sum2 += merr * merr; ecount++;
printf(" %7.2f %5g %14.6f %10.3e \n", Tmu[i], rhomu[i], mout, merr);
}
cout << div2;
RMS2 = sqrt(sum2 / ecount); // RMS2 includes last six points near critical point
cout << "Relative errors above should be on the order of 1E-8 or lower, except near the critical point, where they\n";
cout << "may be as high as 8.417E-2. This is due to the critical enhancement, mu2, being set to 1, per IAPWS guidance\n";
cout << "for industrial use. RMS error for first eleven points is " << scientific << setprecision(3) << RMS1;
cout << " (should be 1.095e-8 or less)." << endl;
cout << "RMS error for last six points is " << fixed << setprecision(2) << RMS2 * 100.0 << "% near the critical point." << endl << endl << endl;
// ******************************************************************************
// THERMAL CONDUCTIVITY Verification Values from IAPWS R15-11
// ******************************************************************************
cout << div2;
cout << " Water Thermal Conductivity Verification \n\n";
cout << "Pressure and Temperature points based on the tabulated\n";
cout << "computer program verification values from [IAPWS R15-11],\n";
cout << "page 13, Tables 7,8,9. Per guidance from IAPWS, all input\n";
cout << "properties are calculated using the standard IF97 forward\n";
cout << "functions and the dimensionless isothermal compressibility,\n";
cout << "zeta, is set to a simplified correlation, resulting in \n";
cout << "slightly greater error in the lower portion of this table,\n";
cout << "very near the critical point.\n";
cout << "This function is temperature, pressure, and density based\n";
cout << "with density determined from the IF97 density function.\n";
cout << div2;
double Tk[13] = {620, 620, 650, 800, 647.35, 647.35, 647.35, 647.35, 647.35, 647.35, 647.35, 647.35, 647.35};
double Pk[13] = {20, 50, 0.3, 50, 21.98406271345, 22.1321600249828, 0.297422657,
19.45771946, 21.98406271, 22.11526557, 22.13216002, 22.15298122, 22.33268694};
double rhok[13] = {613.227777440321, 699.226043285397, 1.00452140735385, 218.030012152047, 222,
322, 1, 122, 222, 272, 322, 372, 422};
double k[13] = {0.481485195, 0.54503894, 0.0522311024, 0.177709914, 0.36687941, 1.24182415, 51.9298924,
130.922885, 367.787459, 757.959776, 1443.75556, 650.319402, 448.883487};
double kout = 0, kerr = 0;
sum2 = 0; ecount = 0;
cout << " T P rho Conductivity error\n";
cout << " [K] [MPa] [kg/m^3] [mW/m/K] [rel]\n";
cout << div2;
for (int i = 0; i < 6; i++) {
kout = tcond_Tp(Tk[i], Pk[i]); // use 2-input function
kerr = abs(kout - k[i]) / k[i];
sum2 += kerr * kerr; ecount++;
printf("%6.2f %11.10g %10.9g %13.7f %10.3e \n", Tk[i], Pk[i], rhok[i], kout*1000.0, kerr);
}
cout << div2;
RMS1 = sqrt(sum2 / ecount); // RMS1 includes first eleven points away from critical point
sum2 = 0; ecount = 0;
for (int i = 6; i < 13; i++) {
kout = tcond_Tp(Tk[i], Pk[i]) * 1000.0 ; // use 2-input function
kerr = abs(kout - k[i]) / k[i];
sum2 += kerr * kerr;
ecount++;
printf("%6.2f %11.10g %10g %13.6f %10.3e \n", Tk[i], Pk[i], rhok[i], kout, kerr);
}
cout << div2;
RMS2 = sqrt(sum2 / ecount); // RMS2 includes last seven points near critical point
cout << "Relative errors above should be on the order of 1E-9 or lower, except near the critical point, where they\n";
cout << "may be as high as 1.4E-1. This is due to the critical enhancement being simplified, per IAPWS guidance\n";
cout << "for industrial use. RMS error for first six points is " << scientific << setprecision(3) << RMS1;
cout << " (should be 1.763e-9 or less)." << endl;
cout << "RMS error for last seven points is " << fixed << setprecision(2) << RMS2 * 100.0 << "% near the critical point." << endl << endl << endl;
// ******************************************************************************
// SURFACE TENSION Verification Values from IAPWS R1-76(2014)
// ******************************************************************************
cout << div2;
cout << " Water Surface Tension Verification \n\n";
cout << "Temperature points based on the tabulated computer program\n";
cout << "verification values from [IAPWS R1-76(2014)],\n";
cout << "pages 4-5, Table 1.\n";
cout << div2;
double Tsig[] = {0.01, 5, 10, 15, 20, 25, 30, 35, 40, 45, 50, 55, 60, 65, 70, 75, 80, 85, 90, 95, 100, 105, 110, 115, 120,
125, 130, 135, 140, 145, 150, 155, 160, 165, 170, 175, 180, 185, 190, 195, 200, 205, 210, 215, 220, 225, 230, 235, 240, 245,
250, 255, 260, 265, 270, 275, 280, 285, 290, 295, 300, 305, 310, 315, 320, 325, 330, 335, 340, 345, 350, 355, 360, 365, 370};
double sig[] = {75.64, 74.94, 74.23, 73.49, 72.74, 71.98, 71.19, 70.41, 69.59, 68.78, 67.93, 67.09, 66.24, 65.36, 64.47,
63.57, 62.68, 61.76, 60.82, 59.88, 58.92, 57.95, 56.97, 55.98, 54.97, 53.96, 52.94, 51.9, 50.86, 49.81,
48.75, 47.67, 46.58, 45.49, 44.4, 43.3, 42.19, 41.07, 39.95, 38.82, 37.68, 36.54, 35.4, 34.24, 33.09,
31.92, 30.76, 29.58, 28.4, 27.22, 26.05, 24.86, 23.66, 22.46, 21.29, 20.14, 18.93, 17.76, 16.6, 15.45,
14.3, 13.18, 12.04, 10.92, 9.81, 8.73, 7.66, 6.61, 5.59, 4.6, 3.64, 2.74, 1.89, 1.12, 0.45};
int nsig = sizeof(Tsig) / sizeof(Tsig[0]);
double sigout = 0, sigerr = 0;
sum2 = 0; ecount = 0;
cout << div2;
cout << " T sigma error\n";
cout << " [K] [mN/m] [rel]\n";
cout << div2;
for (int i = 0; i < nsig; i++) {
sigout = sigma97(Tsig[i] + 273.15) * 1000.0; // convert from N/m to mN/m
sigerr = abs(sigout - sig[i]) / sig[i];
sum2 += sigerr * sigerr;
ecount++;
printf(" %6g %10.2f %10.3e \n", Tsig[i], sigout, sigerr);
}
cout << div2;
RMS1 = sqrt(sum2 / ecount);
cout << "Relative errors above should be on the order of 1E-3 or lower @ T < 260 C\nand on the order of 1E-2 @ T >= 260 C.\n";
cout << "The RMS of all relative errors (" << ecount << ") is " << scientific << setprecision(3) << RMS1 << endl << endl;
return 0;
}