There are some tried, tested and true samples, which can help you understand the usage of xlight libraries and test your hardware components.
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PHOTON_NRF_SENSORS
Very basic demo of NRF2.4 module (don't use it in working project) -
Particle-RF24-MySensors
Particle-RF24-MySensors shows how to use MySensors protocol with transport layer implementation -
curton
Curton control demo on Photon -
particle-rf24
RF2.4 stress test program on Photon -
xlight-stm8s-rftest
RF2.4 stress test program on stm8s